Dinitrobenzonitrile → HCID 66745943, compound

HRID 1467235Notes

Reaction equation

HRID 1467235 reaction equation
[OH:1][CH2:2][C:3]([NH:6][C:7](=[O:14])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)([CH3:5])[CH3:4].[N+:15]([C:18]1[CH:25]=[CH:24][CH:23]=[C:22]([N+]([O-])=O)[C:19]=1[C:20]#[N:21])([O-:17])=[O:16]>>[C:20]([C:19]1[C:18]([N+:15]([O-:17])=[O:16])=[CH:25][CH:24]=[CH:23][C:22]=1[O:1][CH2:2][C:3]([NH:6][C:7](=[O:14])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)([CH3:5])[CH3:4])#[N:21]

Participants

3

Reactant 2

HCID 520718DinitrobenzonitrileHCID 639965benzamide, N-(2-hydroxy-1,1-dimethylethyl)-

Product 1

HCID 66745943HCID 66745943, compoundYield 91%

Procedure

Prepared as in Example 197c from N-(1-hydroxy-2-methylpropan-2-yl)benzamide (Boyd, R. N.; Hansen, R. H. J. Am. Chem. Soc. 1953, 75, 5896) and 2,6-dinitrobenzonitrile in 91% yield as a pale yellow solid. MS 340 (MH+).

Sources & evidence

ORD record
ord-e1fa683b85c0471a8d624125e2a92903
Source dataset
uspto-grants-2015_04
Patent number
US09000054B2

Reaction notes

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