HCID 43808402, compound → HCID 89499967, compound

HRID 1467807Notes

Reaction equation

HRID 1467807 reaction equation
[CH2:1]1[C:10]2[C:5](=[C:6]([N:11]3[CH2:16][CH2:15][CH2:14][CH2:13][C:12]3=[O:17])[CH:7]=[CH:8][CH:9]=2)[CH2:4][CH2:3][NH:2]1>O=[Mn]=O>[CH:1]1[C:10]2[C:5](=[C:6]([N:11]3[CH2:16][CH2:15][CH2:14][CH2:13][C:12]3=[O:17])[CH:7]=[CH:8][CH:9]=2)[CH2:4][CH2:3][N:2]=1

Participants

3

Reactant 1

HCID 43808402HCID 43808402, compound

Product 1

HCID 89499967HCID 89499967, compoundYield 95.6%

Reagents, catalysts & solvents 1

HCID 14801Manganese dioxideCatalyst

Procedure

33B (0.38 g, 1.650 mmol) was oxidized with MnO2 to afford 0.36 g of 33C as a dark oil. MS (ESI) m/z: 229.0 (M+H)+.

Sources & evidence

ORD record
ord-c09773be6c934729811eaf529ebda3c5
Source dataset
uspto-grants-2015_04
Patent number
US09000172B2

Reaction notes

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