Water → HCID 178454901, compound

HRID 1471245Notes

Reaction equation

HRID 1471245 reaction equation
[C:1]([P:5]([C:7]([CH3:10])([CH3:9])[CH3:8])Cl)([CH3:4])([CH3:3])[CH3:2].ClCCl.[OH2:14]>>[C:1]([PH:5](=[O:14])[C:7]([CH3:10])([CH3:9])[CH3:8])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 3

HCID 962WaterHCID 6344DichloromethaneHCID 139566Di-tert-butylchlorophosphine

Product 1

HCID 178454901HCID 178454901, compoundYield 100.2%

Procedure

To a flask were added 1.0 g of di(tert-butyl)chlorophosphine and 5 ml of dichloromethane under nitrogen. After slow addition of 0.25 g of water, the mixture was stirred at 22 C for 30 minutes and the solvent was removed leaving a solid. After purification by sublimation, 0.9 g of a white solid was obtained.

Workup

  1. customthe solvent was removed
  2. customleaving a solid
  3. customAfter purification by sublimation

Sources & evidence

ORD record
ord-2d58c4e962554211b5499e89c57afd5f
Source dataset
uspto-grants-2015_04
Patent number
US09011734B2

Reaction notes

Loading…