HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetaldehyde → HCID 68724806, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetaldehyde | HCID 177 | — |
| Reactant | Lithium diisopropylamide | HCID 2724682 | — |
| Reactant | HCID 68724101 | HCID 68724101 | — |
| Solvent | Methyl t-butylether hexane | HCID 21982663 | — |
| Product | HCID 68724806 | HCID 68724806 | 68% |
Reaction Steps
Prepared in 68% yield after FC (300 g SiO2, hexane/MTBE 4:1 to 3:1) from methyl 1-(7-methylspiro[4.5]deca-6,8-dien-6-yl)ethanone (2.25 g, 11.8 mmol), LDA, acetaldehyde as described in Example 10.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09012391B2 |
| Source dataset | uspto-grants-2015_04 |
| ORD ID | ord-5fabb2cc24ab410788abe5bef0ce871d |
| Source note | uspto-grants-2015_04 |