HRID1472512

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：Brc1ccc(N(c2ccc(-c3ccccc3)cc2)c2ccc(-c3ccccc3)cc2)cc1

HCID11454354

N-([1,1'-Biphenyl]-4-yl)-N-(4-bromophenyl)[1,1'-biphenyl]-4-amine

C30H22BrN

结构：CC1(C)c2cnccc2-n2c3ccc(B(O)O)cc3c3cccc1c32

HCID67201981

未命名化合物

PRODUCTS

生成物

结构：CC1(C)c2cnccc2-n2c3ccc(-c4ccc(N(c5ccccc5)c5ccccc5)cc4)cc3c3cccc1c32

HCID86670685

未命名化合物

PROCEDURE

实验过程

The compound is synthesised by the same procedure as Example 7 by reaction of 36 g (110 mmol) of 8,8-dimethyl-8H-10,12b-diazabenzo[a]aceanthrylene-3-boronic acid with 52 g (110 mmol) of bis-biphenyl-4-yl(4-bromophenyl)amine. The residue is recrystallised from toluene and from CH2Cl2/isopropanol and finally sublimed in a high vacuum. Yield: 65 g (95 mmol), 88% of theory, purity according to HPLC 99.9%.

WORKUP

后处理

customThe residue is recrystallised from toluene and from CH2Cl2/isopropanol

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-a7e6e90fff1d4e6a8736284f187bc874
来源数据集: uspto-grants-2015_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US09012599B2
来源说明: uspto-grants-2015_04

反应 SMILES

[CH3:1][C:2]1([CH3:25])[C:16]2[C:11](=[CH:12][CH:13]=[N:14][CH:15]=2)[N:10]2[C:17]3[C:7]([C:8]4[CH:21]=[C:20](B(O)O)[CH:19]=[CH:18][C:9]=42)=[CH:6][CH:5]=[CH:4][C:3]1=3.[C:26]1(C2C=CC=CC=2)[CH:31]=[CH:30][C:29]([N:32]([C:40]2[CH:45]=[CH:44][C:43](C3C=CC=CC=3)=[CH:42][CH:41]=2)[C:33]2[CH:38]=[CH:37][C:36](Br)=[CH:35][CH:34]=2)=[CH:28][CH:27]=1>>[CH3:1][C:2]1([CH3:25])[C:16]2[C:11](=[CH:12][CH:13]=[N:14][CH:15]=2)[N:10]2[C:17]3[C:7]([C:8]4[CH:21]=[C:20]([C:43]5[CH:42]=[CH:41][C:40]([N:32]([C:33]6[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=6)[C:29]6[CH:30]=[CH:31][CH:26]=[CH:27][CH:28]=6)=[CH:45][CH:44]=5)[CH:19]=[CH:18][C:9]=42)=[CH:6][CH:5]=[CH:4][C:3]1=3