Water → HCID 68210359, compound

Participants

Reaction Steps

3.93 g (15.00 mmol) of 2-bromo-3′-methoxybiphenyl, 5.3 g (16.50 mmol) of 9-ethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)carbazole, and 0.35 g (0.30 mmol) of Pd(PPh3)4 were dissolved in 50 ml of toluene, and 4.77 g (45.00 mmol) of Na2CO3 was put into 25 ml of distilled water and then refluxed and agitated for 5 hours. After the reaction was finished, extraction was performed by dichloromethane, filtering was performed by silica gel, and the column was used at a ratio of hexane:MC=7:3 (v/v) to obtain 3.90 g of 9-ethyl-2-(3′-methoxybiphenyl-2-yl)carbazole (yield 69%).

Provenance & Evidence