HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Octadecene → HCID 86658439, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Octadecene | HCID 8217 | — |
| Reactant | Phosphinic Acid | HCID 4124402 | — |
| Catalyst | 1,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(1,1-diphenylphosphine) | HCID 636044 | — |
| Catalyst | Bis(dibenzylideneacetone)palladium | HCID 9811564 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 86658439 | HCID 86658439 | 98.6% |
Reaction Steps
Example 7 is repeated with 66 g (0.5 mol) of phosphinic acid, 140.0 g (0.5 mol) of octadecene, 23 mg of tris(dibenzylideneacetone)dipalladium and 32 mg of 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene in 500 g of tetrahydrofuran followed by working up to obtain 157 g (85% of theory) of octadecylphosphonous acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09018413B2 |
| Source dataset | uspto-grants-2015_04 |
| ORD ID | ord-531192417d58416cbae173063a42cb99 |
| Source note | uspto-grants-2015_04 |