Dimethyl Disulfide → HCID 86704386, compound

HRID 1476370Notes

Reaction equation

HRID 1476370 reaction equation
[CH2:1]([C:11]1[CH:20]=[C:19]2[C:14]([CH:15]=[CH:16][C:17]([O:21][CH3:22])=[CH:18]2)=[CH:13][CH:12]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[CH3:23][S:24]SC>>[CH2:1]([C:11]1[CH:20]=[C:19]2[C:14]([CH:15]=[C:16]([S:24][CH3:23])[C:17]([O:21][CH3:22])=[CH:18]2)=[CH:13][CH:12]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

3

Reactant 2

HCID 12232Dimethyl DisulfideHCID 86704382HCID 86704382, compound

Product 1

HCID 86704386HCID 86704386, compoundYield 93%

Procedure

7-Decyl-3-methylthio-2-methoxynaphthalene (compound (4)-12) was synthesized from 7-decyl-2-methoxynaphthalene (compound (3)-12) and dimethyl disulfide by the same method as that in Example 14 (yield of 93%, recrystallized from hexane to obtain yellow crystals).

Workup

  1. customin Example 14 (yield of 93%, recrystallized from hexane to obtain yellow crystals)

Sources & evidence

ORD record
ord-852a0e346cf044988c9c4170aec4b3e7
Source dataset
uspto-grants-2015_04
Patent number
US09018630B2

Reaction notes

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