Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hexamethylenediamine | HCID 16402 | — |
| Reactant | 2-Ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid | HCID 25019176 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Trimethylolpropane | HCID 6510 | — |
| Product | HCID 131736528 | HCID 131736528 | — |
Reaction Steps
69.60 g of 1,6-Hexanediamine (HDA) (0.60 mol) was added into a round-bottom flask with a stirring, a reflux condenser and a thermometer, and cooled to 10° C. below under nitrogen. 74.00 g methanol solution of trimethylolpropane triacrylate (TMPTA) (40%, 0.1 mol) was added to the round-bottom flask, and the mixture is allowed to react at 25° C. for 24 hours. The result solution is subjected to vacuum distillation to remove excess 1,6-Hexanediamine (HDA) (0.60 mol) and methanol at 110° C. for 8 hours, to yield 64.46 g of light-amber viscous material, i.e., intermediate trimethylolpropane core, amino terminated dendrimer (TMPTA-HDA-9NH for abbreviation).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09403853B2 |
|---|
| Source dataset | uspto-grants-2016_08 |
|---|
| ORD ID | ord-d50fc7f5a02d410f82ba21d0fb83f4c6 |
|---|
| Source note | uspto-grants-2016_08 |
|---|
