HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1478939Generated: October 30, 2026
Sodium Carbonate → Tris(tris(trimethylsiloxy)silylpropyl)amine
https://huagongshe.com/reaction/1478939
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | (3-Aminopropyl)tris(trimethylsiloxy)silane | HCID 2756547 | — |
| Reactant | 3-Iodopropyl-tris(trimethylsiloxy)silane | HCID 22325693 | — |
| Solvent | Dimethylacetamide | HCID 31374 | — |
| Product | Tris(tris(trimethylsiloxy)silylpropyl)amine | HCID 86670505 | — |
Reaction Steps
14.3 g of 3-iodopropyltris(trimethylsiloxy)silane (28), 5.7 g of 3-aminopropyltris(trimethyl-siloxy)silane and 9.6 g of sodium carbonate are added to 50 ml dimethylacetamide and stirred for 15 hours at 80° C. The dimethylacetamide is then evaporated and the residue taken up in methylene chloride. The organic phase is washed with water, dried and evaporated. The product is purified by column chromatography on silica gel to give 7 g of a slightly yellowish oil of formula (30); 1H-NMR (ppm, CDCl3): 2.21 6H t, 1.38 6H txt, 0.28 6H t, 0 81H s.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09403987B2 |
|---|
| Source dataset | uspto-grants-2016_08 |
|---|
| ORD ID | ord-8f5669107d6e42f5a259c26cffdf9dd8 |
|---|
| Source note | uspto-grants-2016_08 |
|---|
