HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1479013Generated: October 31, 2026
Triethyl phosphite → HCID 54498727, compound
https://huagongshe.com/reaction/1479013
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Triethyl phosphite | HCID 31215 | — |
| Reactant | Methyl 2-(bromomethyl)benzoate | HCID 2734813 | — |
| Product | HCID 54498727 | HCID 54498727 | 104.7% |
Reaction Steps
A mixture of 2-bromomethyl-benzoic acid methyl ester (5 g; 21.83 mmol; 1 eq.) and phosphorous acid triethyl ester (4.53 mL; 26.19 mmol; 1.2 eq.) was stirred at 150° C. for 16 hours then concentrated in vacuo to afford the title compound (6.54 g, quantitative) a yellow oil. HPLC (max plot) 88.8%; Rt 3.11 min.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09403835B2 |
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| Source dataset | uspto-grants-2016_08 |
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| ORD ID | ord-4f4a0cffbcef4d40b588988f830e48e9 |
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| Source note | uspto-grants-2016_08 |
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