HCID 89580709, compound → HCID 72291823, compound

HRID 1479738Notes

Reaction equation

HRID 1479738 reaction equation
[CH3:1][C:2]([CH3:15])=[C:3]([C:5]1[CH:14]=[CH:13][C:8]([C:9]([O:11][CH3:12])=[O:10])=[CH:7][CH:6]=1)[CH3:4].[H][H]>CO.[Pd]>[CH3:1][CH:2]([CH3:15])[CH:3]([C:5]1[CH:6]=[CH:7][C:8]([C:9]([O:11][CH3:12])=[O:10])=[CH:13][CH:14]=1)[CH3:4]

Participants

5

Reactant 2

HCID 89580709HCID 89580709, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 72291823HCID 72291823, compoundYield 100%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

To a solution methyl 4-(3-methylbut-2-en-2-yl)benzoate (0.2 g, 1.0 mmol) in methanol (30 mL) was added Pd/C (0.50 g). The reaction mixture was stirred at room temperature for 3 hour at 4 atm of hydrogen, after the reaction, it was filtered, and the filtrate was removed in vacuo to give pure product methyl 4-(3-methylbutan-2-yl)benzoate (0.20 g, 100%) as the colorless oil.

Workup

  1. customafter the reaction, it
  2. filtrationwas filtered
  3. customthe filtrate was removed in vacuo

Sources & evidence

ORD record
ord-46d42c728dfa48b4aa7d5243213a34a6
Source dataset
uspto-grants-2016_08
Patent number
US09409865B2

Reaction notes

Loading…