Toluene → HCID 86682765, compound

Participants

Reaction Conditions

Reaction Steps

6-(fluoranthene-3-yl)naphthalene trifluoromethane sulfonate (0.16 g, 0.33 mmol), boronic acid (0.054 g, 0.36 mmol) and Pd(PPh3)4 (0.194 g, 0.17 mmol) were placed in a 2-neck RB flask and placed under nitrogen atmosphere. Toluene (25 mL) and Dimethoxyethane (25 mL) was then added to the reaction mixture followed by aq. Na2CO3 (2 M, 1.0 ml). The reaction mixture was refluxed at 85° C. for 24 h and diluted with Toluene and filtered through a celite bed. The combined organic extracts was evaporated to dryness and purified by silica column chromatography using dichloromethane and pet-ether (40-60° C.) to give slightly yellow coloured powder the product (0.05 g).

Provenance & Evidence