Water → HCID 117820069, compound

HRID 1482762Notes

Reaction equation

HRID 1482762 reaction equation
[CH2:1]([C@H:6]([N:10]([CH2:15][C:16]([O-:18])=[O:17])[CH2:11][C:12]([O-:14])=[O:13])[C:7]([O-:9])=[O:8])[CH2:2]C([O-])=O.[Na+].[Na+].[Na+].[Na+].[OH2:23]>>[C:12]([OH:14])(=[O:13])[CH2:11][N:10]([CH2:15][C:16]([OH:18])=[O:17])[C@H:6]([C:7]([OH:9])=[O:8])[C@@H:1]([CH3:2])[OH:23]

Participants

3

Reactant 2

HCID 962WaterHCID 44630158Tetrasodium N,N-bis(carboxymethyl)-L-glutamate

Product 1

HCID 117820069HCID 117820069, compoundYield 85%

Procedure

The solution obtained in example 1 was acidified using an ion exchange resin. Acidification took place using Amberlite IR-120, a strong acid ion exchange resin: 55 g of GLDA solution, 110 g of Amberlite IR-120 as such, and ca 100 g of water were stirred in a 500 ml round-bottomed flask for at least 48 h. After filtering off the resin the solution was dried by evaporation of water at reduced pressure at 70° C. The light-coloured crispy foam obtained was further dried in a vacuum oven at 65° C. This resulted in a solid product in a yield of circa 85%.

Workup

  1. filtrationAfter filtering off the resin the solution
  2. dry with materialwas dried by evaporation of water at reduced pressure at 70° C
  3. customThe light-coloured crispy foam obtained
  4. customwas further dried in a vacuum oven at 65° C
  5. customThis resulted in a solid product in a yield of circa 85%

Sources & evidence

ORD record
ord-897d36df93a142d186f6ac42e5715b27
Source dataset
uspto-grants-2016_08
Patent number
US09416095B2

Reaction notes

Loading…