2-Chloroaniline → HCID 118292559, compound

Participants

Reaction Conditions

Reaction Steps

Under an argon atmosphere, 7.0 g of 3-bromofluoranthene, 4.76 g of 2-chloroaniline, 0.46 g of tris(dibenzylideneacetone) dipalladium(0), 0.58 g of tri-t-butylphosphine tetrafluorohydroborate, 3.4 g of sodium t-butoxide, and 200 mL of dry toluene were charged in a flask, and the resultant mixture was stirred under heating at 80° C. for 8 h. After cooling to room temperature, the reaction solution was extracted with toluene and the extract was filtered through celite. The filtrate was concentrated and the residue was purified by silica gel column chromatography to obtain 6.14 g of 3-(2-chloroanilino)fluoranthene (yield: 75%).

Provenance & Evidence