HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Hydroxybenzaldehyde → HCID 178472489, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Hydroxybenzaldehyde | HCID 126 | — |
| Reactant | 1-(Bromomethyl)-4-chlorobenzene | HCID 69329 | — |
| Reactant | Ethyl 4-hydroxycyclohexanecarboxylate | HCID 86973 | — |
| Reactant | (Bromomethyl)cyclobutane | HCID 2734658 | — |
| Product | HCID 178472489 | HCID 178472489 | — |
| Product | HCID 178472490 | HCID 178472490 | — |
Reaction Steps
Instead of 4-hydroxybenzaldehyde and (bromomethyl)cyclobutane, ethyl 4-hydroxycyclohexanecarboxylate (2.00 g) and 4-chlorobenzylbromide (2.86 g) were respectively used and treated by the same technique as in Reference Example 9-1 to give ethyl cis-4-[(4-chlorobenzyl)oxy]cyclohexanecarboxylate as a colorless oil (0.33 g) and ethyl trans-4-[(4-chlorobenzyl)oxy]cyclohexanecarboxylate as a pale yellow oil (0.47 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09422240B2 |
| Source dataset | uspto-grants-2016_08 |
| ORD ID | ord-aed76dc29433422586c1689c0fbca0d6 |
| Source note | uspto-grants-2016_08 |