HCID 67451075, compound → HCID 67451678, compound

HRID 1485594Notes

Reaction equation

HRID 1485594 reaction equation
[CH:1]1[C:13]2[N:12]([C:14]3[CH:23]=[C:22]([C:24]([O:26]C)=O)[C:21]([N:28]4C5C=CC=CC=5[C:34]5[C:29]4=[CH:30][CH:31]=[CH:32][CH:33]=5)=[CH:20][C:15]=3[C:16]([O:18]C)=O)[C:11]3[C:6](=CC=CC=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[C:41]1([Li])[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=1>>[CH:45]1[C:46]2[N:28]([C:21]3[CH:20]=[C:15]([C:16]([OH:18])([C:41]4[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=4)[C:41]4[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=4)[C:14]([N:12]4[C:11]5[CH:34]=[CH:29][CH:30]=[CH:31][C:6]=5[C:5]5[C:13]4=[CH:1][CH:2]=[CH:3][CH:4]=5)=[CH:23][C:22]=3[C:24]([C:13]3[CH:1]=[CH:2][CH:3]=[CH:4][CH:5]=3)([C:14]3[CH:23]=[CH:22][CH:21]=[CH:20][CH:15]=3)[OH:26])[C:29]3[C:30](=[CH:31][CH:32]=[CH:33][CH:34]=3)[C:41]=2[CH:42]=[CH:43][CH:44]=1

Participants

3

Reactant 2

HCID 67451075HCID 67451075, compoundHCID 178506676HCID 178506676, compound

Product 1

HCID 67451678HCID 67451678, compound

Procedure

The compound is synthesised by the same procedure as for the corresponding step of Example 5 by reaction of 73 g (140 mmol) of dimethyl 2,5-biscarbazol-9-ylterephthalate with 400 ml (600 mmol) of 1.6 M phenyllithium solution. The yield is 89 g (115 mmol), corresponding to 82% of theory.

Sources & evidence

ORD record
ord-a9c4a9be780642c081e6361cc61aa53c
Source dataset
uspto-grants-2016_08
Patent number
US09422287B2

Reaction notes

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