HuagongsheHuagongshe Chemistry Print Report · For research reference only
alpha-Acetobromogalactose → (2R,3S,4S,5R)-2,3,4,5,6-pentahydroxyhexanal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | alpha-Acetobromogalactose | HCID 2734143 | — |
| Reactant | HCID 18634526 | HCID 18634526 | — |
| Reactant | 51224-13-6 | HCID 86698937 | — |
| Product | (2R,3S,4S,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 3037556 | — |
Reaction Steps
The galactose coupling agent 2-imino-2-methoxyethyl-1-thio-β-D-galactopyranoside (9) was prepared starting from 2,3,4,6-tetra-O-acetyl-α-D-galactopyranosyl bromide (6) in 3 steps via the intermediates 2-S-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-2-thiouronium bromide (7) and cyanomethyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-galactopyranoside (8) as shown in FIG. 5.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09427482B2 |
| Source dataset | uspto-grants-2016_08 |
| ORD ID | ord-d0651a71b4ee49ab9375955a96e518e4 |
| Source note | uspto-grants-2016_08 |