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HRID1488245

反应详情

EQUATION

反应方程式

HRID 1488245 的结构方程式

REACTANTS

反应物

1
反应SMILES：[N-]=[N+]=NCCO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]2O)[C@@H]1O
HCID117995942

未命名化合物

PRODUCTS

产物

1
反应SMILES：NCCO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O[C@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]2O)[C@@H]1O
HCID117996458

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
反应SMILES：[Pd]
催化剂HCID23938

Palladium

Pd

反应SMILES：CO.O
溶剂HCID22242641

Methanol--water (1/1)

CH6O2

CONDITIONS

反应条件

温度
25 °C

PROCEDURE

实验过程

In a 50 mL round bottom flask, 2-azidoethyl 3-O-α-D-mannopyranosyl-α-D-mannopyranoside (139 mg, 0.338 mmol) was dissolved in water/CH3OH (v/v 1:1, 5 mL). To the above solution was added Pd/C (10%, 36 mg, 0.034 mmol). The reaction mixture was stirred at 25° C. under H2 balloon for 18 hr. The mixture was filtered through a pad of Celite, and the filtrate was concentrated to give the title compound. LC-MS Method A: m/e=386.08 [M+1]; Rt=0.24 min.

WORKUP

后处理

  1. filtrationThe mixture was filtered through a pad of Celite
  2. concentrationthe filtrate was concentrated