HCID 131736872, compound → HCID 69865256, compound

Participants

Reaction Steps

A mixture of benzyl[2-(β-D-mannopyranosyloxy)ethyl]carbamate (133 mg, 0.372 mmol), and Pd/C (20 mg, 0.019 mmol) in water (5 mL) was allowed to stir under a balloon of H2 at rt for 4 hr. The catalyst was filtered off and washed with H2O (3×5 mL). The fitrate was concentrated to give the title compound. 1H NMR (CD3OD) δ 4.53-4.52 (1H, m), 3.93-3.85 (3H, m), 3.72-3.64 (2H, m), 3.53-3.49 (1H, m), 3.44-3.42 (1H, m), 3.22-3.18 (1H, m), 2.92-2.85 (2H, m).

Provenance & Evidence