4-(4-Chloro-4-silacyclohexyl)-1-n-propylbenzene → HCID 178439126, compound

HRID 1489813Notes

Reaction equation

HRID 1489813 reaction equation
[F:1][CH2:2][CH2:3][CH2:4][SiH:5]1[CH2:10][CH2:9][CH:8](Br)[CH2:7][CH2:6]1.Cl[SiH:13]1[CH2:18][CH2:17][CH:16]([C:19]2[CH:24]=[CH:23][C:22]([CH2:25][CH2:26][CH3:27])=[CH:21][CH:20]=2)[CH2:15][CH2:14]1.Cl[SiH]1CCC(C2C=CC(OC(F)(F)F)=CC=2)CC1>>[F:1][CH2:2][CH2:3][CH2:4][Si@H:5]1[CH2:10][CH2:9][C@H:8]([Si@H:13]2[CH2:18][CH2:17][C@H:16]([C:19]3[CH:20]=[CH:21][C:22]([CH2:25][CH2:26][CH3:27])=[CH:23][CH:24]=3)[CH2:15][CH2:14]2)[CH2:7][CH2:6]1

Participants

4

Reactant 3

HCID 1232766524-(4-Chloro-4-silacyclohexyl)-1-n-propylbenzeneHCID 1232976064-(4-Chloro-4-silacyclohexyl)-1-trifluoromethoxybenzeneHCID 1239359844-(3-Fluoropropyl)-4-silacyclohexylbromide

Product 1

HCID 178439126HCID 178439126, compound

Procedure

The above compound was obtained in the same manner as Example 23, using 4-(3-fluoropropyl)-4-silacyclohexylbromide and 4-(4-chloro-4-silacyclohexyl)-1-n-propylbenzene instead of 4-(4,4-difluorobutyl)-4-silacyclohexylbromide and 4-(4-chloro-4-silacyclohexyl)-1-trifluoromethoxybenzene, respectively.

Workup

  1. customThe above compound was obtained in the same manner as Example 23

Sources & evidence

ORD record
ord-45c4f70b2e5f4115ba3d07d2c91b9b3d
Source dataset
uspto-grants-1997_10
Patent number
US05679746

Reaction notes

Loading…