HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenol → Diphenyl carbonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenol | HCID 996 | — |
| Reactant | Phenyl chloroformate | HCID 15891 | — |
| Catalyst | Vanadium carbide | HCID 159387 | — |
| Product | Diphenyl carbonate | HCID 7597 | — |
Reaction Steps
Example 1 was repeated with 14.1 g of a powdered vanadium carbide from H. C. Starck at 140° C. After 2 hours' reaction time, phenol conversion was 16.3%, wherein 0.3 g of phenyl chloroformate and 25.5 g of diphenyl carbonate were formed. Selectivity for carbonates was 98.2%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05679825 |
| Source dataset | uspto-grants-1997_10 |
| ORD ID | ord-d460fbf1e4a54770a2012a78d752a795 |
| Source note | uspto-grants-1997_10 |