HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenol → Diphenyl carbonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenol | HCID 996 | — |
| Reactant | Phenyl chloroformate | HCID 15891 | — |
| Catalyst | Methane--molybdenum (1/2) | HCID 159430 | — |
| Product | Diphenyl carbonate | HCID 7597 | — |
Reaction Steps
Example 1 was repeated with 14.1 g of a dimolybdenum carbide from H. C. Starck at 140° C. After 2 hours' reaction time, phenol conversion was 6.0%, wherein 5.1 g of phenyl chloroformate and 5.8 g of diphenyl carbonate were formed. Selectivity for carbonates was 97.3%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05679825 |
| Source dataset | uspto-grants-1997_10 |
| ORD ID | ord-a3bd51a1fbd94c939eb91ab88923c7f5 |
| Source note | uspto-grants-1997_10 |