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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490074Generated: November 2, 2026

Aniline → N-Allylaniline

https://huagongshe.com/reaction/1490074

Reaction equation

Participants

RoleNameHCIDCharge
ReactantAnilineHCID 6115—
ReactantAllyl bromideHCID 7841—
Reactant2,2,2-Trifluoro-N-phenylacetamideHCID 67881—
ProductN-AllylanilineHCID 68525—

Reaction Steps

N-Allylaniline [NMR (200 MHz, DMSO-d6): δ 3.68 (t, J=5.2 Hz, 2H); 5.10 (d, J=10.2 Hz, 1H); 5.23 (d, J=17.2 Hz, 1H); 5.78 (br s, 1H); 5.75-5.97 (m, 1H); 6.52 (t, J=7.3 Hz, 2H); 6.56 (d, J=7.8 Hz, 2H); 7.06 (t, J=7.3 Hz, 2H)] was prepared from aniline and allyl bromide via trifluoroacetanilide using the general method described by Hodge (Harland, P. A.; Hodge, P; Maughan, W.; Wildsmith, E. Synthesis, 1984, 941).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05681830
Source datasetuspto-grants-1997_10
ORD IDord-ee40bd9f533a4b4986277298ab3b568f
Source noteuspto-grants-1997_10