HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490434Generated: October 30, 2026
2-Methylbenzimidazole → 2-Methyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-benzimidazole
https://huagongshe.com/reaction/1490434
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 2-Methylbenzimidazole | HCID 11984 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 2-Methyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-benzimidazole | HCID 46738035 | 27% |
Provenance & Evidence
| DOI | 10.1021/ja412563e |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-edb44184ad9b4e1bac0d47308a0f2c0f |
|---|
| Source note | Borylation dataset from Roche |
|---|