HuagongsheHuagongshe Chemistry Print Report · For research reference only
N,N-Dimethylaniline → N,N-dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N,N-Dimethylaniline | HCID 949 | — |
| Reagent | Pinacol | HCID 6425 | — |
| Reagent | Triethylamine | HCID 8471 | — |
| Reagent | Catecholborane | HCID 67506 | — |
| Catalyst | Methylium, triphenyl-, tetrakis(2,3,4,5,6-pentafluorophenyl)borate(1-) (1:1) | HCID 9832824 | — |
| Product | N,N-dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline | HCID 2758659 | 80% |
Reaction Conditions
| Temperature | 100 °C |
|---|
Provenance & Evidence
| DOI | 10.1002/anie.201611536 |
|---|---|
| Source dataset | Borylation dataset from Roche |
| ORD ID | ord-b4cbd3df40c848cf8e5f7ec5db1e68eb |
| Source note | Borylation dataset from Roche |