HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490504Generated: October 31, 2026
HCID 24754943, compound → HCID 56924968, compound
https://huagongshe.com/reaction/1490504
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 24754943 | HCID 24754943 | — |
| Reagent | Pinacol | HCID 6425 | — |
| Reagent | Triethylamine | HCID 8471 | — |
| Reagent | Catecholborane | HCID 67506 | — |
| Catalyst | Tris(pentafluorophenyl)borane | HCID 582056 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 56924968 | HCID 56924968 | 75% |
Reaction Steps
Prepared from 5-methyl-N-(triisopropylsilyl)-1H-indole (4d, 57.5 mg, 0.200 mmol, 1.00 equiv) and catBH (96.0 mg, 0.800 mmol, 4.00 equiv) according to GP 2. The title compound was purified by flash column chromatography using cyclohexane/EtOAc/Et3N (30/1/1) as eluent to afford 6d[S4] (62.0 mg, 75%) as a white foam.
Provenance & Evidence
| DOI | 10.1002/anie.201611536 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-147ffd4a44b54602a4cf9c7f7939ea78 |
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| Source note | Borylation dataset from Roche |
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