Benzofuran → 2-(1-Benzofuran-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

HRID 1490579Notes

Reaction equation

HRID 1490579 reaction equation
c1ccc2occc2c1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OBOC1(C)C.CCCCCC.C[OH2+].C[OH2+].[Ir].[Ir]>CC1(C)OB(c2cc3ccccc3o2)OC1(C)C

Participants

6

Reactant 1

HCID 9223Benzofuran

Product 1

HCID 113685332-(1-Benzofuran-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneYield 82%

Reagents, catalysts & solvents 4

HCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 42491874,4'-Di-tert-butyl-2,2'-bipyridylReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8058HexaneSolvent

Conditions

Temperature
25 °C

Sources & evidence

ORD record
ord-940670c2d8584f4c980fc4ad87c21f1a
Source dataset
Borylation dataset from Roche

Reaction notes

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