HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490627Generated: October 31, 2026
3-Methylbenzaldehyde → (3-Formyl-5-methylphenyl)boronic acid pinacol ester
https://huagongshe.com/reaction/1490627
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-Methylbenzaldehyde | HCID 12105 | — |
| Reagent | Tert-Butylamine | HCID 6385 | — |
| Reagent | 3,4,7,8-Tetramethyl-1,10-phenanthroline | HCID 74265 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | (3-Formyl-5-methylphenyl)boronic acid pinacol ester | HCID 127263689 | 79% |
Provenance & Evidence
| DOI | 10.1021/jacs.5b11683 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-02e529dadf584eb2ad65978440415c1a |
|---|
| Source note | Borylation dataset from Roche |
|---|
