HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490635Generated: October 30, 2026
4-Chlorobenzaldehyde → 2-Chloro-5-formylphenylboronic acid pinacol ester
https://huagongshe.com/reaction/1490635
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 4-Chlorobenzaldehyde | HCID 7726 | — |
| Reagent | Methylamine | HCID 6329 | — |
| Reagent | 3,4,7,8-Tetramethyl-1,10-phenanthroline | HCID 74265 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 2-Chloro-5-formylphenylboronic acid pinacol ester | HCID 74789452 | 66% |
Provenance & Evidence
| DOI | 10.1021/jacs.5b11683 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-e4acf71b3bbf4c67a83758fdc9d37d5a |
|---|
| Source note | Borylation dataset from Roche |
|---|
