HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490647Generated: November 1, 2026
Benzoic acid, 3-fluoro-, ethyl ester → Ethyl 3-fluoro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
https://huagongshe.com/reaction/1490647
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Benzoic acid, 3-fluoro-, ethyl ester | HCID 67975 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | Ethyl 3-fluoro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate | HCID 23134230 | 27% |
Provenance & Evidence
| DOI | 10.1021/jacs.6b13346 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-8806275e9a12481eb728ad106eba28c6 |
|---|
| Source note | Borylation dataset from Roche |
|---|
