HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490693Generated: October 30, 2026
3-Chlorophenol → 5-Chloro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
https://huagongshe.com/reaction/1490693
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-Chlorophenol | HCID 7933 | — |
| Reagent | Pinacol | HCID 6425 | — |
| Reagent | Triethylamine | HCID 8471 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Reagent | 2,2'-Bi-1,3,2-dioxaborolane | HCID 18673254 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Toluene | HCID 1140 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | 5-Chloro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol | HCID 67609314 | 60% |
Provenance & Evidence
| DOI | 10.1021/jacs.7b02232 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-b199553eaea14cafaf9a87b64267fbe0 |
|---|
| Source note | Borylation dataset from Roche |
|---|
