HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490911Generated: October 31, 2026
7-Bromo-2-methylquinoline → HCID 178422398, compound
https://huagongshe.com/reaction/1490911
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 7-Bromo-2-methylquinoline | HCID 12332896 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | tert-Butyl methyl ether | HCID 15413 | — |
| Product | HCID 178422398 | HCID 178422398 | 52% |
| Product | HCID 178422496 | HCID 178422496 | 28% |
Reaction Steps
Application of general procedure A with 7-bromo-2-methylquinoline (221 mg, 1.00mmol) afforded a mixture of 2 monoborylated products in a 65:35ratio, as determined by GC-MS.
Provenance & Evidence
| DOI | 10.1039/c2sc20776a |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-c929c013efd04889bc74482e72cb999d |
|---|
| Source note | Borylation dataset from Roche |
|---|
