HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490917Generated: October 31, 2026
HCID 82573215, compound → HCID 178422401, compound
https://huagongshe.com/reaction/1490917
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 82573215 | HCID 82573215 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | tert-Butyl methyl ether | HCID 15413 | — |
| Product | HCID 178422401 | HCID 178422401 | 78% |
Reaction Steps
Application of general procedure A(but with a reaction time of 0.25 hours)with 2-methylquinoline-7-carbonitrile (168 mg, 1.00mmol) afforded a mixture of 2 monoborylated and 1 bisborylated product in an 82:9:9ratio, as determined by GC-MS.
Provenance & Evidence
| DOI | 10.1039/c2sc20776a |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-866a6d3063904e86bbbfa0f6dbabb9f0 |
|---|
| Source note | Borylation dataset from Roche |
|---|
