Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 2-Methylanisole | HCID 33637 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | tert-Butyl methyl ether | HCID 15413 | — |
| Product | HCID 21923912 | HCID 21923912 | 19% |
| Product | HCID 69938122 | HCID 69938122 | 56% |
Reaction Steps
General procedure Cwas applied to 1-methoxy-2-methylbenzene 15b(50mg, 0.4mmol). The reaction mixture was stirredat room temperature for 16hours giving a conversion of 75% (GC-MS) and 16band 17bin a 75:25mixture which also contained unreacted starting material 15b(1H NMR spectrum).
Provenance & Evidence
| DOI | 10.1039/c2sc20776a |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-d706495cb5eb4f489882e939c637fd65 |
|---|
| Source note | Borylation dataset from Roche |
|---|
