HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490933Generated: October 30, 2026
1-Tetralone → 6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydronaphthalen-1(2H)-one
https://huagongshe.com/reaction/1490933
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1-Tetralone | HCID 10724 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | tert-Butyl methyl ether | HCID 15413 | — |
| Product | HCID 68473465 | HCID 68473465 | 20% |
| Product | 6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydronaphthalen-1(2H)-one | HCID 71303839 | 80% |
Reaction Steps
General procedure Dwas applied to 3,4-dihydronaphthalen-1(2H)-one15i(29mg, 0.2mmol). The reactionmixture was allowed to stand for 16hoursgiving a conversion of >99% (GC-MS) and 16iand 17iin a 80:20mixture (1H NMR spectrum).
Provenance & Evidence
| DOI | 10.1039/c2sc20776a |
|---|
| Source dataset | Borylation dataset from Roche |
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| ORD ID | ord-f3741a9c10d54b95a8a57098ee379e4e |
|---|
| Source note | Borylation dataset from Roche |
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