HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491046Generated: October 31, 2026
HCID 3577044, compound → HCID 178454434, compound
https://huagongshe.com/reaction/1491046
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 3577044 | HCID 3577044 | — |
| Reagent | 3,4,7,8-Tetramethyl-1,10-phenanthroline | HCID 74265 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Cyclohexane | HCID 8078 | — |
| Product | HCID 178454434 | HCID 178454434 | 7% |
Reaction Steps
1b (200 mg, 1.6 mmol) and HBpin (0.34 mL, 2.4 mmol) were used. Purification was performed by MPLC (hexane/ethyl acetate = 7:3 to 3:7) to afford a mixture of 1b and 2b (NMR yield 7%). The mixture was purified again by GPC to afford 2b as a white solid.
Provenance & Evidence
| DOI | 10.1002/anie.201409186 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-bbd54f9e2cdf406083aec23c7938046d |
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| Source note | Borylation dataset from Roche |
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