HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491047Generated: October 31, 2026
HCID 3412875, compound → HCID 178431001, compound
https://huagongshe.com/reaction/1491047
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 3412875 | HCID 3412875 | — |
| Reagent | 3,4,7,8-Tetramethyl-1,10-phenanthroline | HCID 74265 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Cyclohexane | HCID 8078 | — |
| Product | HCID 178431001 | HCID 178431001 | 3% |
Reaction Steps
1d (200 mg, 1.2 mmol) and HBpin (0.26 mL, 1.8 mmol) were used. Purification was performed by MPLC (hexane/ethyl acetate = 7:3 to 2:3) to afford a mixture of 1d and 2d (NMR yield 3%). The mixture was purified again by GPC to afford 2d as a white solid. 1
Provenance & Evidence
| DOI | 10.1002/anie.201409186 |
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| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-a31aef1a5072446b863d5adb1a29b4f2 |
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| Source note | Borylation dataset from Roche |
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