HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491050Generated: October 30, 2026
HCID 103713505, compound → HCID 178439604, compound
https://huagongshe.com/reaction/1491050
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 103713505 | HCID 103713505 | — |
| Reagent | 3,4,7,8-Tetramethyl-1,10-phenanthroline | HCID 74265 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Cyclohexane | HCID 8078 | — |
| Product | HCID 178439604 | HCID 178439604 | 23% |
Reaction Steps
1j (15.0 mg, 81 µmol) and HBpin (17.8 µL, 0.12 mmol) were used. Purification was performed by MPLC (hexane/ethyl acetate = 9:1 to 7:3, then hexane/ether = 1:1 to 0:1), and finally by GPC to afford 5.9 mg of 2j as a colorless oil in a 23% yield. NOE was observed between H-1 and H-3 and not observed between H-1 and H-2. This result indicates that 2j has cis configuration between the N group and the B group
Provenance & Evidence
| DOI | 10.1002/anie.201409186 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-84a1619a2aaa485aa3d6761aec50cd2f |
|---|
| Source note | Borylation dataset from Roche |
|---|
