HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491131Generated: October 25, 2026
(Ethylthio)benzene → HCID 178477269, compound
https://huagongshe.com/reaction/1491131
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | (Ethylthio)benzene | HCID 12144 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | 2-(2-(Ethylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 123787969 | 24% |
| Product | HCID 178477269 | HCID 178477269 | 30% |
Reaction Steps
dtbpy: The mixture of product (110 mg, 83% yield, ortho/meta + para = 0.29); meta- and para- isomers (5b+5bʹ) were obtained by further purification of the crude mixture by GPC (77 mg, 58% yield), colorless oil;
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-3cf848853d454210a4ad7b64186a1c6e |
|---|
| Source note | Borylation dataset from Roche |
|---|
