関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 3-Methoxythioanisole | HCID 281182 | — |
| 試薬 | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| 試薬 | Bis(pinacolato)diborane | HCID 2733548 | — |
| 触媒 | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| 溶媒 | P-Xylene | HCID 7809 | — |
| 生成物 | 2-(3-Methoxy-5-(methylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 53217246 | 69% |
反応手順
dtbpy: A mixture of ortho- and meta-borylated products (97 mg, 69% yield, ortho/meta + para = <0.01); meta-Isomer 5i were obtained by further purification by GPC (92 mg, 66% yield), white solid (mp. 73-75 oC)
情報源と証拠
| DOI | 10.1002/anie.201610041 |
|---|
| 出典データセット | Borylation dataset from Roche |
|---|
| ORD ID | ord-bc30bcc9f8fa4078b52bc21fad6778ea |
|---|
| 出典メモ | Borylation dataset from Roche |
|---|
