HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491148Generated: November 1, 2026
3-Ethyl-(1-thiaethyl)-benzene → HCID 177499506, compound
https://huagongshe.com/reaction/1491148
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-Ethyl-(1-thiaethyl)-benzene | HCID 14944133 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 2-Pyridin-2-yl-5-[2-[4-(trifluoromethyl)-1,3,2-dioxaborolan-2-yl]phenyl]pyridine | HCID 134956623 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 177499506 | HCID 177499506 | 88% |
Reaction Steps
Ligand 3f: A mixture of ortho- and meta-borylated products (122 mg, 88% yield, ortho/meta + para = >30); ortho-borylated product 4k was obtained by further purification by GPC (111 mg, 80% yield), colorless oil;
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-62cafbeae78042f3a2ec3f143cfb6c2c |
|---|
| Source note | Borylation dataset from Roche |
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