HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491149Generated: October 29, 2026
3-Ethyl-(1-thiaethyl)-benzene → HCID 164891978, compound
https://huagongshe.com/reaction/1491149
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-Ethyl-(1-thiaethyl)-benzene | HCID 14944133 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 164891978 | HCID 164891978 | 74% |
Reaction Steps
Yield: A mixture of ortho- and meta-borylated products (103 mg, 74% yield, ortho/meta + para = <0.01); meta-Isomer 5k was obtained by further purification by GPC (93 mg, 67% yield), colorless oil;
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-07735c61c2ba4303a5458fefe94b7ddd |
|---|
| Source note | Borylation dataset from Roche |
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