HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491151Generated: November 2, 2026
HCID 21355295, compound → HCID 163198000, compound
https://huagongshe.com/reaction/1491151
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 21355295 | HCID 21355295 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 163198000 | HCID 163198000 | 63% |
Reaction Steps
dtbpy: A mixture of ortho- and meta-borylated products (92 mg, 63% yield, ortho/meta + para = <0.01); meta-Isomer 5l was obtained by further purification by GPC (86 mg, 59% yield), white solid (mp. 60-62 oC)
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-46778eed6d4a4c90a502f4cd22d334ae |
|---|
| Source note | Borylation dataset from Roche |
|---|
