HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491153Generated: November 1, 2026
HCID 12498845, compound → HCID 178503075, compound
https://huagongshe.com/reaction/1491153
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 12498845 | HCID 12498845 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 178503075 | HCID 178503075 | 78% |
Reaction Steps
dtbpy: A mixture of ortho- and meta-borylated products (126 mg, 78% yield, ortho/meta + para = <0.01); meta-Isomer 5m was obtained by further purification by GPC (114 mg, 71% yield), colorless oil;
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-acc450e0bf2b43d4b06181299b20954c |
|---|
| Source note | Borylation dataset from Roche |
|---|
