HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491159Generated: October 25, 2026
Methyl 3-(methylthio)benzoate → HCID 178498626, compound
https://huagongshe.com/reaction/1491159
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Methyl 3-(methylthio)benzoate | HCID 6432769 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 178498626 | HCID 178498626 | 83% |
Reaction Steps
dtbpy: A mixture of ortho- and meta-borylated products (128 mg, 83% yield, ortho/meta + para = <0.01); meta-Isomer 5pwas obtained by further purification by GPC (116 mg, 75% yield), white solid (mp. 115-117 oC)
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-76f3f83feb2744bb84a39a38dd5be253 |
|---|
| Source note | Borylation dataset from Roche |
|---|
