HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491161Generated: November 2, 2026
HCID 85587722, compound → HCID 178503071, compound
https://huagongshe.com/reaction/1491161
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 85587722 | HCID 85587722 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 178503071 | HCID 178503071 | 85% |
Reaction Steps
dtbpy: A mixture of ortho- and meta-borylated products (136 mg, 85% yield, ortho/meta + para = <0.01); meta-Isomer 5q was obtained by further purification by GPC (127 mg, 79% yield), colorless oil;
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-e5c9824ec85e4337b939b002ac010109 |
|---|
| Source note | Borylation dataset from Roche |
|---|
