HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491163Generated: November 1, 2026
HCID 85765608, compound → HCID 178503070, compound
https://huagongshe.com/reaction/1491163
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 85765608 | HCID 85765608 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 178503070 | HCID 178503070 | 92% |
Reaction Steps
dtbpy: A mixture of ortho- and meta-borylated products (148 mg, 92% yield, ortho/meta + para = <0.01); meta-Isomer 5r was obtained by further purification by GPC (125 mg, 78% yield), white solid (mp. 52-54 oC)
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-ca1b5259ec4f40a7976d05531a67fdc6 |
|---|
| Source note | Borylation dataset from Roche |
|---|
