HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491165Generated: October 30, 2026
3-(Methylsulfanyl)benzonitrile → HCID 177677472, compound
https://huagongshe.com/reaction/1491165
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-(Methylsulfanyl)benzonitrile | HCID 13032813 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 177677472 | HCID 177677472 | 82% |
Reaction Steps
dtbpy: A mixture of ortho- and meta-borylated products (112 mg, 82% yield, ortho/meta + para = <0.01); meta-Isomer 5s was obtained by further purification of the crude mixture by GPC (67 mg, 60% yield), white solid (mp. 75-77 oC);
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-0dc5c76273764473a9c47b34bf982241 |
|---|
| Source note | Borylation dataset from Roche |
|---|
