HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491167Generated: October 31, 2026
HCID 155019327, compound → HCID 178503072, compound
https://huagongshe.com/reaction/1491167
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 155019327 | HCID 155019327 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 178503072 | HCID 178503072 | 63% |
Reaction Steps
dtbpy: A mixture of ortho- and meta-borylated products (101 mg, 63% yield, ortho/meta + para = <0.01); meta-Isomer 5t was obtained by further purification by GPC (86 mg, 54% yield), yellow oil;
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-519e8158e30f492ca483d4296809dc10 |
|---|
| Source note | Borylation dataset from Roche |
|---|
